Polythionic acids form from sulfide scales exposed to oxygen and water in the stainless steel that are sensitized which can occur in most stainlesssteel tube materials after exposures to temperatures in excess of 700f to 1500f 371c to 815c during manufacturing, fabrication or in service. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. A thermal stabilization treatment at 899 900 deg c for two hours is specified for increasing the corrosion resistance to intergranular corrosion and polythionic acid stress corrosion cracking. Stress corrosion cracking scc caused by polythionic acid andor chlorides has occurred in coal liquefaction pilot plants.
This paper discusses ae results of activepath dissolutiontype scc of austenitic stainless steel in chloride solution and fused salt, fluoride and polythionic acid solutions, brass in ammonia mattossons solution. Pascc is fairly easy to find with penetrant testing. In this chapter, the conditions for the occurrence of scc are first introduced. Resistant to chloride and polythionic acid stress corrosion cracking. Scc is the brittle cracking of a metal due to the result of combined effects from localized corrosion and tensile stress. Cracking of sensitized stainless steels inspectioneering. Polythionic acid is an oxoacid which has a straight chain of sulfur atoms and has the chemical formula s n so 3 h 2 n 2. Alloy for resistance to polythionic acid stress corrosion. Any acid of the form h2sno6 having a chain of sulfur atoms. Ae monitoring from various types of stress corrosion cracking scc has been conducted for the past 15 years in our laboratory. Stress corrosion cracking scc is the formation and growth of crack. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Standard practice for evaluating stresscorrosioncracking.
Electrochemical characteristics of polythionic acid stress corrosion cracking have been examined mainly on sensitized type 304 stainless steel. Chemical studies of polythionic acid stresscorrosion cracking. Why does chloride stress corrosion cracking and pascc only. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. An electrochemical study on stress corrosion cracking of. Ctlpolythionic stress corrosion cracking of stainless. This theory implies that if surface energy is reduced, then. Stress corrosion cracking by krittin rattakham youtube. Photomicrographs will be shown that demonstrate the lack of grain boundary sensitization, and also the lack of grain boundary ditching in the oxalic acid test. This phenomenon is usually an internal problem, occurring on the processexposed side of a piping run, vessel shell, exchanger bundle, heater tube. This paper discusses ae results of activepath dissolutiontype scc of austenitic stainless steel in chloride solution and fused salt, fluoride and polythionic acid solutions, brass.
What are the industrial practices being followed in. The polythionic acid sulfurous acid and hydrogen sulfide environment provides a way of evaluating the resistance of stainless steels and related alloys to intergranular stress corrosion cracking. The alloy is, however, susceptible to intergranular polythionic acid stress corrosion cracking. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing. The probable role of low levels of chloride ions or sulfurcontaining ions is described including the relationship to polythionic acid cracking. Pdf polythionic acid corrosion in refinery hydroprocessors. Stress corrosion cracking issues in syngas plants that may. Stress corrosion cracking susceptibility of stainless. This standard is directed toward preventing stress corrosion. This standard practice provides mitigation methods to protect austenitic stainless steels and other austenitic alloys from polythionic acid pta stress corrosion cracking scc that can occur during a shutdown of refinery equipment. Decreasing the carbon content shifted the sensitization curve to longer times.
Alloy for resistance to polythionic acid stress corrosion cracking for. The higher temperature limit for acid copper sulfate was significantly higher than for polythionic acid so the more standard acid copper sulfate test can be used for control. Stress corrosion cracking of sensitized 304 austenitic. Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these days, most refiners reduce their susceptibility to pascc by selecting resistant alloys. On the other hand, polyesters are readily degraded by acids, and scc is a likely failure mechanism. Learn vocabulary, terms, and more with flashcards, games, and other study tools. This practice can be applied to wrought products, castings, weld metal of stainless steel or other materials that are used in environments.
Presence of cr, carbon, exposure temperatures and presence of polythionic acids play an important role in stress corrosion cracking. Stress corrosion cracking scc caused by polythionic acid andor chlorides has. Chemical studies of polythionic acid stress corrosion cracking. All of the cracks observed were found underneath the coke deposits. Polythionic acid may be present in petrochemical environments. Various separations downstream remove the acid gases, particulate matter. Tcr engineering mumbai corrosion testing, nace, astm. Severe stress corrosion cracking was observed in the csbp ltd, western australia 304l unlagged stainless steel absorber column of a nitric acid plant after 15 years of plant operation. Stress corrosion cracking of sensitized austenitic stainless steels in kuwait petroleum refineries. A shutdown includes the actual down time period and the contiguous periods required to shut down and start up the equipment. The next line of defence in controlling stress corrosion cracking is testing to be sure that materials are safe on a batchbybatch. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain conditions. Pdf stress corrosion cracking of sensitized austenitic. Soda ash washing can be a costly and time consuming endeavor for the refiner.
Polythionic acid corrosion in refinery hydroprocessors. The austenitic stainless steel tubes in these services can be susceptible to polythionic acid stress corrosion cracking. Trithionic acid h 2 s 3 o 6, tetrathionic acid h 2 s 4 o 6 are simple examples. Stress corrosion cracking of sensitized type 304 steel in low temperature borated water has been observed. The cracking was found when rust stainingleaks were observed. If not specified earlier, meeting a 262 practice c would be really tough, while practice e could be relatively easy. Stress corrosion cracking of sensitized austenitic. Stress corrosion cracking scc can occur in a most metals and alloys due to the combined action of corrosion, tensile stress residual or applied and a susceptible microstructure. Figure 4 shows the results of polythionic acid stress corrosion cracking test following astm g35 on 347ap, tp321, and tp347 without stabilization. At lower ph the dissolved hydrogen cyanide hcn and ammonium cyanide. Samans, stress corrosion cracking susceptibility of stainless steels and nickelbase alloys in polythionic acids and acid copper sulfate solution, corrosion. Polythionic acid stress corrosion cracking pascc is an affliction of many refineries. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. The test may not be relevant to stress corrosion cracking in polythionic acid or caustic environments.
The stress corrosion cracking sco of sensitized type 304 stainless steel in thiosulfate. Stress corrosion cracking scc may be defined as the delayed failure of alloys by cracking when exposed to certain environments in the presence of a static tensile stress. However, to avoid scc in austenitic ss steels, exposure to conducive environment polythionic acid formation in presence of oxygenwaterchlorides along with metal sulfidesh2s to be reduced by adopting. The corrosion rate tests at ambient temperature indicated corrosion. The astm standard for a376 and a 312 gives this treatment for the stabilzed grade austenitic stainless steels as a supplementary requirement without. Protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during shutdown of refinery equipment. Stressed sensitized 304, 316, and 321 stainless steels were selected and subjected to various environments that. Stress corrosion cracking can lead to catastrophic brittle failure. Developed as a material to resist corrosion attack in phosphoric acid processing, the grades chemical composition ensures superior performance in a wide range of demanding conditions.
The most common fluid causing intergranular corrosion in hydrocarbon plants is polythionic acid. Abstractlow temperature stress corrosion cracking of sensitized stainless steel, promoted by aqueous solutions of polythionates sxo, and related sulfur compounds. Stress corrosion cracking investigations on ubend samples of sensitized 304 austenitic stainless steel have been conducted in sulfurous acid solutions in the concentration range, 0. Refinery environment assisted cracking flashcards quizlet. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Both austenitic and straight chromium grades of stainless steels can be attacked by polythionic acid. The chemical environment that causes scc for a given alloy is often one which is only mildly corrosive to the metal. In certain process units, such as hydrocracking, soda ash washing neutralization of austenitic stainless steel is required during turnarounds to mitigate the potential for polythionic acid stress corrosion cracking pta scc.
It is twis wealth of knowledge in corrosion and the effects of hydrogen on the properties of materials, combined with our testing facilities and broad experience in the field of metallurgy and corrosion which sets us apart from our competitors in stress corrosion cracking scc testing. Polythionic acid stress corrosion cracking deterioration. C for one hour, no intergranular corrosion was observed in tp321 and tp347 welded joints. The test solution was prepared by passing sulfur dioxide gas into deionized water for 4 hours and then bubbling hydrogen sulfide for 3 hours. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. The importance of a conjoint action of corrosion and stress as well as the nature of.
Stress corrosion cracking is the growth of crack formation in a corrosive environment. If the cracking has been correctly diagnosed as chloride stress corrosion cracking, and the problem is confined to small drain, flush fittings, etc. Effects of sensitization and service fluid chemistry on. Based on this analysis the leaks were caused by cracks that initiated on the id surface. The alloys 321 and 347 are particularly useful under conditions which cause polythionic acid stress corrosion of nonstabilized austenitic stainless steel, such as alloy 304.
An austenitic stainless steel for sulfuric acid corrosion environments. Stresscorrosion cracking, materials performance and. These characteristics are consistent with stress corrosion cracking due to polythionic acids. Preface thispresentvolumeisthefirstofatwopartseriesonstresscorrosioncrackingplannedbythe advancedresearchprojectsagencyforthedesigner. Low temperature stress corrosion cracking of sensitized stainless steel, promoted by aqueous solutions of polythionates s xo 6 2. Carbonate cracks are suface breaking flaws that are predominantly intergranular in nature and typically occur in aswelded carbon steel fabrications as a network of very fine, oxidefilled cracks similar in appearance to caustic stress corrosion cracking and amine stress corrosion cracking. Heat treatment method for reducing polythionic acid stress. Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these days, most refiners reduce their susceptibility to pascc by selecting resistant alloys orby neutralizing exposed surfaces during shutdowns. Stress corrosion cracking susceptibility of stainless steels and. The terminology sensitization, which is generally used to discuss intergranular corrosion cracking behaviors, has different metallurgical meanings depending on intergranular corrosion test methods such as strauss, electrochemical potentiokinetic reacitivationepr and wackenroeder test. What are the industrial practices being followed in refineries to mitigate polythionic acid corrosion in furnaces. Stress corrosion cracking facts and how to reduce the. The cracks are intergranular and narrow with no significant branching. Exposure of nonstabilized austenitic stainless steel pipe to temperatures in the sensitizing range will cause the precipitation of chromium carbides at grain boundaries.
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